The Science behind Solar Power
What happens when light strikes on a solar cell?
What is the process that causes the change from light into electricity?
The answer is photovoltaic
effect.
A simple explanation on
Photovoltaic Effect:
1. Sunlight hits on a solar cell.
2. Electrons in semiconductors are excited and start
to move.
3. When electrons moves in a direction, electrics
are generated.
Take a look inside the Solar Cell:
At a closer look;
Energy
Contained in Sunlight
Sunlight,
or any light, travels in forms of packets, which are photons. Each photon contains different amount of energy. We can
only see some of the "light" that is emitted by Sun. For example, in
the visible light, red had the
lowest energy while violet has the highest energy. In terms of invisible
"light", ultraviolet has higher energy while infrared has lower
energy compared to visible lights.
When
sunlight strikes on a solar cell, it is actually these photons that are
striking on the solar cell. Some of the energy is absorbed and even more is
lost. So where does these energies go?
Semiconductors
The
energy absorbed goes to the semiconductors in the solar cell. Solar cells are mainly
made of semiconductors. Why semiconductors?
P-Type
and N-Type Semiconductor
Silicon
is the most common semiconductor. However, a normal semiconductor is not
enough. A process which is called "doping" is needed to create P-type semiconductor and N-type semiconductor.
Doping
is a process to insert elements that has three
valence electrons, for example Boron as shown below, into silicon and form
P-Type semiconductor, or insert elements that has five valence electrons into
silicon and form N-Type semiconductor.
![]() |
From left to right: Basic Structure of N-Type Semiconductor and P-type Semiconductor |
N-Type Semiconductor (Antimony - Sb) | P-Type Semiconductor (Boron - B) |
---|---|
1. Antimony has 5 valence electrons 2. Antimony act as donor atoms 3. Silicon has 4 valence electrons 4. An additional freely moving electron is "created" |
1. Boron has 3 valence electrons 2. Boron act as acceptor atoms 3. Silicon has 4 valence electrons 4. An additional freely moving "hole" is "created" |
With additional freely moving electron and additional
electron "hole", electron can jump from atom to atom much more
easily, resulting in higher electric conductivity.
Combining N-Type
Semiconductor and P-Type Semiconductor
A
"p-n junction" is formed
when p-type semiconductor and n-type semiconductor is combined. This is due to
the "holes" are positively charged while electrons are negatively
charged. "Holes" and electrons start travelling to p-type and n-type
semiconductors respectively.
When
a substantial amount of "holes" and electrons travel to another
semiconductor, they leave the opposite charges at their "home
semiconductor". Positive charge will form at n-type semiconductor and
negative charge will form at p-type semiconductor. When there is difference in
charge, there is an electric field moving from positive to negative.
Since
electron is n-type semiconductor is negatively charged, they will be repelled
from the p-n junction. The same scenario works for the p-type semiconductor. Sometimes
there will have some electrons or "holes" diffuse back into
"home semiconductor" but eventually equilibrium is reached and the
net flow of electron or holes in and out from p-n junction is the same.
This
raises a question: "If net flow of electron is zero, which means net flow
of current is zero, how do we generate electricity?"
That is why sunlight is
needed to come into play!
Back to when Sunlight strikes
the Solar Cells
When
photons strikes on the solar cell with enough energy, some of the bond in the semiconductor can be
broken. This happens in both p-type and n-type semiconductor. When a bond is
broken, electron is released and at the same time, "holes" are
created. There will be a lot of bond broken so there will be a lot of free electrons
and "holes". Some of these electrons will recombine with their holes,
which releases heat energy.
Other
electrons and holes will generate electricity. As mentioned above, there is an
electric field in the p-n junction, consisting the positive charges and
negative charges. "Holes" will move towards negative charges while
electrons will move towards positive charge. In short, "holes" and
electrons are separated in different direction.
A
solar cell does not only consist of semiconductors, we need to connect it with
a circuit. The circuit will also be connected to the electrical appliances, for
example light bulbs. Since the "holes" and electrons are separated
due to electric field they will travel around in the circuit and go back to the
solar cell.
Thus, electricity is
generated!
To have an overall view
on how does electricity is generated; it is advisable to watch the video below:
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References:
MERTENS, K. (2013)
Photovoltaics: Fundamentals, Technology and Practice, Hoboken, John Wiley and
Sons.
KALTSCHMITT, M.,
STREICHER, W. & WIESE, A. (2007). Renewable Energy: Technology, Economics
and Environment, Heidelberg, Springer.
Written by: Yeap Weng Yeow
Thank you for sharing valuable information. Nice post. I enjoyed reading this post.
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